Agreed. Almost every time I've looked deeply into stdlib code I was surprised by how hard to follow it is and how frequently antipatterns are employed. Doubly so for anything near a C module.
I consider the Python stdlib in a similar vein as the C++ stdlib or Boost: Yes, some useful bits in there, but (1) lots of rot (2) you don't want to have your code look anything like it.
Though core has some bad API due to maintaining backwards compatibility a lot of the third party libraries like requests, Flask have great focus on API design and code quality.
Agreed with the rest, I've ended up reading pypy's implementation of some functions sometimes to see how it works after trying CPython first. From the few I've read I'd say pypy looks nice by the way (I'm talking about standard library).